As published on Torsten Curdt’s weblog you can use IRC style commands on Skype chat windows.
Here is a list of commands which you can use on Skype :
/add [skypename]
/help
/topic [new topic]
/me
/history
/leave
/goadmin
/get creator
/get role
/whois [skypename]
/setrole [skypename] MASTER|HELPER|USER|LISTENER
/kick [skypename]
/kickban [skypename]
/get guidelines
/set guidelines [text]
/get options [text]
/set options [[+|-]flag] …
/setpassword [password] [password hint]
/clearpassword
/get password_hint
/set password_hint [text]
/set password [text]
/get banlist
/get allowlist
/set banlist [[+|-]mask] …
/set allowlist [[+|-]mask] …
/alertson [text to match]
/alertsoff
/call [skypename[,skypename,...]]
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Windows Live Messenger
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My name is Deniz Akay and I live in
Thanks. Some more commands are directly on the Skype-site https://support.skype.com/en_GB/faq/FA10042/What-are-chat-commands-and-roles or with more explainations on http://kosi2801.freepgs.com/2008/12/20/skype_chat_commands.html